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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：吉林大学
学位：博士
所在单位：化工学院
学科：有机化学. 应用化学. 物理化学
办公地点：西部校区E座208房间
联系方式：0411－84986236
电子邮箱：zhaojzh@dlut.edu.cn
Ruthenium(II) Polyimine-Coumarin Dyad with Non-emissive (IL)-I-3 Excited State as Sensitizer for Triplet-Triplet Annihilation Based Upconversion
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论文类型：期刊论文
发表时间：2011-08-29
发表刊物：ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
收录刊物：PubMed、Scopus、SCIE、EI
卷号：50
期号：36
页面范围：8283-8286
ISSN号：1433-7851
关键字：coumarin; electronic structure; photochemistry; ruthenium; upconversion
摘要：Light out of darkness? Most sensitizers for triplet-triplet annihilation (TTA) upconversion are strongly phosphorescent. A new RuII-coumarin dyad, on the other hand, has a non-emissive 3IL excited state (φP=0.2%) but shows a good upconversion quantum yield (φUC=2.7%, see picture, TTET=triplet-triplet energy transfer). © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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