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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：吉林大学
学位：博士
所在单位：化工学院
学科：有机化学. 应用化学. 物理化学
办公地点：西部校区E座208房间
联系方式：0411－84986236
电子邮箱：zhaojzh@dlut.edu.cn
6,6 '-Bis-substituted BINOL boronic acids as enantio selective and chemoselective fluorescent chemosensors for D-sorbitol
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论文类型：期刊论文
发表时间：2008-02-11
发表刊物：TETRAHEDRON
收录刊物：SCIE
卷号：64
期号：7
页面范围：1309-1315
ISSN号：0040-4020
关键字：BINOL boronic acid; chiral recognition; enantioselective sensors; sugar alcohols
摘要：A new chiral fluorescent BINOL boronic acid 1 has been synthesized. The chiral recognition properties of 1 are drastically different from BINOL boronic acid c. Sensor 1 shows improved enantioselectivity as well as chemoselectivity toward sugar alcohols, such as D-sorbitol and D-mannitol. The enantioselectivity of sensor 1 toward D-sorbitol (K-R/K-S) is 1:35 (pH 9.0), and the chemoselectivity for D-sorbitol/D-mannitol is 20:1. (c) 2007 Elsevier Ltd. All rights reserved.