赵亮
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个人信息Personal Information
副研究员
博士生导师
硕士生导师
毕业院校:大连理工大学
学位:博士
所在单位:化工学院
学科:精细化工. 应用化学. 无机化学
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个人简介Personal Profile
赵亮,理学博士,大连理工大学精细化工全国重点实验室副研究员,博士生导师。
2008年获得大连理工大学学士学位并保送精细化工国家重点实验室直接攻读博士学位。2011年获国家留学基金委公派资格,于美国University of Massachusetts联合培养,2014年获得大连理工大学博士学位并加入精细化工全国重点实验室。教育部智能材料化工前沿科学中心光响应智能配位聚合物创新团队和教育部“仿生识别与荧光传感”创新团队及科技部创新人才推进计划创新团队青年骨干。2017年入选大连市高层次人才创新支持计划,荣获大连市青年五四奖章(集体)。2018、2021年连续入选大连理工大学星海人才培育计划。先后承担国家重点研发计划子课题、国家自然科学基金委面上项目、青年项目以及博士后科学基金,参与国家自然科学基金重点项目、国家重点研发计划课题及科技部重点基础研究发展计划(973计划)子课题。主要从事功能化配位超分子体系的可控构筑及仿生催化研究。以第一或通讯作者在J. Am. Chem. Soc.(4篇)、Angew. Chem. Int. Ed.(5篇)、Nature Commun.(4篇)、ACS Catal.、Small、J. Mater. Chem. A等国际知名期刊上发表学术论文 50 余篇,4篇入选Editor’s Highlights,多篇文章被 J. Am. Chem. Soc.、Angew. Chem. Int. Ed.杂志选为封面,授权国家发明专利 15 项。受邀担任J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Chem、Adv.Mater.、Coord. Chem. Rev.等20余种国际学术期刊审稿人。
研究方向:
1、金属-有机笼(MOCs)的可控组装及光催化与仿生催化
2、多功能金属-有机框架材料(MOFs)的构筑与仿生催化
3、功能化共价有机框架材料(COFs)的设计与光催化研究
4、金属-有机笼与天然酶超分子体系协同催化级联反应
热诚欢迎有志于投身科研事业的同学踊跃加盟,有意者请发送简历至zhaol@dlut.edu.cn,期待您的真诚合作。
荣誉称号:
1、大连理工大学“星海人才培育计划”— 星海优青(2018年、2021年)
2、大连市高层次人才“创新支持计划”— 青年科技之星(2017年)
3、大连市青年五四奖章(2017年)
教学科研奖励:
1、辽宁省自然科学学术成果奖一等奖(2015、2018、2019年)
2、辽宁省教学成果奖一等奖(2020年)
3、大连理工大学教学质量优良奖(2025年)
代表性论文:
42. S. Liu, G. Ji, Y. Wang, L. Zhao,* C. He, C. Liu, and C. Duan, Ultrafine Sub‑1 nm One-Dimensional Coordination Polymer Nanowires for Boosting Photocatalytic Functionalization of Inert C(sp3)−H Bonds, J. Am. Chem. Soc., 2026, 148, doi.org/10.1021/jacs.5c21627.
41. H. Wang, Y. Zhang, L. Zhao,* C. Wang, C. He, and C. Duan, NADH Mimic-Decorated Coordination Capsules for Biomimetic Capture of NO and Electrocatalytic Reduction to NH3, Angew. Chem. Int. Ed., 2026, 65(6), e19123. (Cover Paper)
40. Q. Song, Y. Zhang, L. Zhao,* Z. Wang, C. He, P. Feng, and C. Duan, Dual Cofactor Co-Decorated Covalent Organic Framework as an Electron Transfer Regulator for Biomimetic Dioxygen Activation, Angew. Chem. Int. Ed., 2025, 64(35), e202508030.
39. H. Wang, Y. Zhang, G. Ji, J. Wei, L. Zhao,* C. He, and C. Duan,* Reserving Electrons in Cofactor Decorated Coordination Capsules for Biomimetic Electrosynthesis of α-Hydroxy/amino Esters, J. Am. Chem. Soc., 2024, 146(43), 29272−29277. (Cover Paper)
38. Z. Wang, Y. Tang, S. Liu, L. Zhao,* H. Li, C. He, and C. Duan,* Energy Transfer-Mediated Multiphoton Excitation for Selective Oxidation of C(sp3)−H Bonds with Coordination Polymer, Nat. Commun., 2024, 15(1), 8813.
37. J. Wei, L. Zhao,* Y. Zhang, G. Han, C. He, C. Wang, and C. Duan,* Enzyme Grafting with a Cofactor-Decorated Metal−Organic Capsule for Solar-to-Chemical Conversion, J. Am. Chem. Soc., 2023, 145(12), 6719−6729.
36. G. Ji, L. Zhao,* J. Wei, J. Cai, C. He, Z. Du, W. Cai, and C. Duan,* A Metal−Organic Framework as a Multiphoton Excitation Regulator for the Activation of Inert C(sp3)−H Bonds and Oxygen, Angew. Chem. Int. Ed., 2022, 61(2), e202114490. (Hot Paper, Editor’s Highlights)
35. J. Cai, L. Zhao,* C. He, Y. Li, and C. Duan,* A Host−Guest Semibiological Photosynthesis System Coupling Artificial and Natural Enzymes for Solar Alcohol Splitting, Nat. Commun., 2021, 12(1), 5092. (Editor’s Highlights)
34. L. Zhao, J. Cai, Y. Li, J. Wei, and C. Duan,* A Host−Guest Approach to Combining Enzymatic and Artificial Catalysis for Catalyzing Biomimetic Monooxygenation, Nat. Commun., 2020, 11(1), 2903. (Editor’s Highlights)
33. J. Wei, L. Zhao,* C. He, S. Zheng, J. N. H. Reek, and C. Duan,* Metal−Organic Capsules with NADH Mimics as Switchable Selectivity Regulators for Photocatalytic Transfer Hydrogenation, J. Am. Chem. Soc., 2019, 141(32), 12707−12716.
32. L. Zhao, J. Wei, J. Zhang, C. He,* C. Duan,* Encapsulation of a Quinhydrone Cofactor in the Inner Pocket of Cobalt Triangular Prisms: Combined Light−Driven Reduction of Protons and Hydrogenation of Nitrobenzene, Angew. Chem. Int. Ed., 2017, 56(48), 15284−15288.
31. L. Zhao, J. Wei, J. Lu, C. He,* C. Duan,* Renewable Molecular Flasks with NADH Models: Combination of Light−Driven Proton Reduction and Biomimetic Hydrogenation of Benzoxazinones, Angew. Chem. Int. Ed., 2017, 56(30), 8692−8696.
30. H. Wang, B. Xing, S. Wang, Y. Zhang, J. Wang, L. Zhao,* and C. Duan, Noble metal-free triphenylamine-based coordination capsule with NADH mimics as a renewable vessel for enhanced biomimetic hydrogenation, Inorg. Chem. Front., 2026, 13, doi.org/10.1039/D6QI00196C.
29. R. Wang, R. Zhang, K. Jin, Y. Li, C. Duan, L. Zhao,* Ruthenium(II)-Catalyzed C−H Allylation of N,N-Dialkyl Thiobenzamides with Allyl Methyl Carbonate by Sulfur Coordination, Synlett, 2025, 36(07), 849−852.
28. H. Li, S. Liu, G. Ji, C. He, Y. Wang, H. Gao, L. Zhao* and C. Duan, In-Situ Exfoliation of Copper-Based Metal−Organic Framework for Boosting Synergistic Photoactivation of Inert C(sp3)−H Bonds and Oxygen, J. Mater. Chem. A, 2024, 12(30), 19069−19080.
27. H. Gao, Y. Tang, S. Liu, C. He, H. Li, L. Zhao,* and C. Duan, Eosin Y Post-Decorated Metal−Organic Framework as a Selectivity Regulator for the Alcohols Oxidation, ACS Appl. Mater. Interfaces, 2024, 16(29), 37896−37905.
26. L. Zhao, Y. Zhang, H. Wang, J. Wang, C. He, L. Zhao,* and C. Duan, Isolation of Copper Photocatalyst on Metal−Organic Cage for the Sulfonylation of Aryl Halides by Visible-Light Mediated C(sp2)−S Cross-Coupling, Chem. Commun., 2024, 60(53), 6805−6808.
25. Z. Wang, Q. Song, C. He, P. Feng, L. Zhao,* and C. Duan, Naphthalene-Based Donor−Acceptor Covalent Organic Frameworks as Electron Distribution Regulator for Boosting Photocatalysis under Green Light Irradiation, Chem. Commun., 2024, 60(36), 4793−4796.
24. G. Ji, L. Zhao,* Y. Tang, S. Liu, Y. Wang, C. He, and C. Duan, Ultrathin Two-Dimensional Cerium-Based Metal−Organic Framework Nanosheet that Boosts Selective Oxidation of Inert C(sp3)−H Bond through Multiphoton Excitation, Small, 2023, 19(26), 2300597.
23. Y. Zhang, L. Zhao,* J. Wei, G. Ji, H. Wang, C. He, L. Zhao, and C. Duan,* Dye-Binding Metal−Organic Cage for Highly Efficient Multiphoton Activation of C(sp3)−H Bonds, ACS Mater. Lett., 2023, 5(8), 2263−2269.
22. Y. Wang, L. Zhao,* S. Liu, G. Ji, C. He, Y. Tang, and C. Duan, A Mixed-Component Metal−Organic Framework for Boosting Synergistic Photoactivation of C(sp3)−H and Oxygen, ACS Appl. Mater. Interfaces, 2023, 15(13), 16744−16754.
21. Y. Tang, G. Ji, H. Li, H. Gao, C. He, L. Zhao* and C. Duan, Ligand-Regulated Photoinduced Electron Transfer within Metal−Organic Frameworks for Efficient Photocatalysis, Inorg. Chem. Front., 2023, 10(18), 5439−5451.
20. J. Wei, L. Zhao,* Y. Zhang, P. Zhou, G. Liu, and C. Duan, Light-Switched Selective Catalysis with NADH Mimic Functionalized Metal−Organic Capsules, Chem. Commun., 2023, 59(1), 71−74.
19. G. Ji, L. Zhao,* Y. Wang, Y. Tang, C. He, S. Liu, and C. Duan, A Binuclear Cerium-Based Metal−Organic Framework as an Artificial Monooxygenase for the Saturated Hydrocarbons Aerobic Oxidation with High Efficiency and High Selectivity, ACS Catal., 2022, 12(13), 7821−7832. (Cover Paper)
18. J. Cai, L. Zhao,* Y. Li, C. He, C. Wang, and C. Duan,* Binding of Dual-Function Hybridized Metal−Organic Capsule to Enzymes for Cascade Catalysis, JACS Au, 2022, 2(7), 1736−1746. (Highlights)
17. Y. Wang, L. Zhao,* G. Ji, C. He, S. Liu, and C. Duan, Vanadium(VIV)-Porphyrin-Based Metal−Organic Frameworks for Synergistic Bimetallic Activation of Inert C(sp3)−H Bonds, ACS Appl. Mater. Interfaces, 2022, 14(2), 2794−2804.
16. Y. Tang, L. Zhao,* G. Ji, Y. Zhang, C. He, Y. Wang, J. Wei, and C. Duan, Ligand Regulated Metal−Organic Frameworks for Synergistic Photoredox and Nickel Catalysis, Inorg. Chem. Front., 2022, 9(13), 3116−3129. (Cover Paper)
15. L. Zhao,* W. Cai, G. Ji, J. Wei, Z. Du, C. He, and C. Duan, Anthraquinone-Based Metal−Organic Framework as a Bifunctional Photocatalyst for C−H Activation, Inorg. Chem., 2022, 61(25), 9493−9503. (Cover Paper)
14. L. Zhao,* Z. Du, G. Ji, Y. Wang, W. Cai, C. He, and C. Duan, Eosin Y-Containing Metal−Organic Framework as a Heterogeneous Catalyst for Direct Photoactivation of Inert C−H Bonds, Inorg. Chem., 2022, 61(19), 7256−7265.
13. Y. Wang, Z. Zhou, L. Zhao,* C. He, W. Sun, and C. Duan,* Ir-Porphyrin-Based Metal−Organic Framework as a Dual Metalloand Photocatalyst for Inert Alkyl C(sp3)−H Bond Activation and Direct Functionalization, ACS Appl. Mater. Interfaces, 2021, 13(9), 10925−10932.
12. L. Zhao,* S. Chu, J. Cai, J. Wei, Y. Li, C. Duan, Metal−Organic Triangles with NADH Mimics for Photocatalytic Hydrogen Production, Chinese J. Inorg. Chem., 2021, 37(5), 769−777.
11. Y. Li, L. Zhao,* J. Cai, C. Duan, Coumarin-Based Metal−Organic Cage for Recognition of Glucosamine, Fine Chemicals, 2021, 38(10), 2004−2011.
10. L. Zhao, Xu Jing, X. Li, X. Guo, Le Zeng, C. He,* C. Duan, Catalytic Properties of Chemical Transformation within the Confined Pockets of Werner-Type Capsules, Coord. Chem. Rev., 2019, 378, 151−187. (Highly Cited)
9. J. Cai, L. Zhao,* J. Wei, C. He, S. Long, C. Duan,* Negatively Charged Metal−Organic Hosts with Cobalt Dithiolene Species: Improving PET Processes for Light−Driven Proton Reduction Through Host−Guest Electrostatic Interactions, Chem. Commun., 2019, 55(59), 8524−8527. (Cover Paper)
8. S. Zheng, L. Zhao*, J. Wei, C. He, G. Liu, C. Duan, A New Cobalt Triangular Prism Supramolecular Flask: Encapsulation of a Quinhydrone Cofactor for Hydrogenation of Nitroarenes with High Selectivity and Efficiency, Inorg. Chem. Commun., 2019, 109, 107558.
7. L. Zhao, J. Wang, P. Wu, C. He, X. Guo, C. Duan,* DHPA−Containing Cobalt-Based Redox Metal−Organic Cyclohelicates as Enzymatic Molecular Flasks for Light−Driven H2 Production, Sci. Rep., 2017, 7, 14347.
6. L. Zhao, J. Wei, F. Zhang, C. He, S. Zheng, C. Duan,* Redox−Active Copper Triangles as an Enzymatic Molecular Flask for Light−Driven Hydrogen Production, RSC Adv., 2017, 7(77), 48989−48993.
5. L. Zhao, X. Wu, X. Wang, C. Duan, H. Wang, A. Punjabi, Y. Zhao, Y. Zhang, Z. Xu, H. Gao,* G. Han,* Development of Excipient−Free Freeze−Dryable Unimolecular Hyperstar Polymers for Efficient siRNA Silencing, ACS Macro Lett., 2017, 6(7), 700−704.
4. L. Zhao, Y. Chu, C. He, C. Duan,* Fluorescent Detection of RDX within DHPA−Containing Metal−Organic Polyhedra, Chem. Commun., 2014, 50(26), 3467−3469.
3. L. Zhao, Y. Liu, C. He,* J. Wang, C. Duan,* Coordination−Driven Nanosized Lanthanide "Molecular Lanterns" as Luminescent Chemosensors for the Selective Sensing of Magnesium Ions, Dalton Trans., 2014, 43(1), 335−343.
2. L. Zhao, A. Kutikov, J. Shen, C. Duan, J. Song,* and G. Han,* Stem Cell Labeling using Polyethylenimine Conjugated (α-NaYbF4:Tm3+)/CaF2 Upconversion Nanoparticles, Theranostics, 2013, 3(4), 249−257. (Cover Paper)
1. L. Zhao, Siyi Qu, C. He,* Rong Zhang and C. Duan, Face-Driven Octanuclear Cerium(IV) Luminescence Polyhedra: Synthesis and Luminescent Sensing Natural Saccharides, Chem. Commun., 2011, 47(33), 9387−9389.
