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个人信息Personal Information
副研究员
博士生导师
硕士生导师
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：精细化工. 应用化学. 无机化学
联系方式：0411-84986476
电子邮箱：zhaol@dlut.edu.cn
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Redox-active copper triangles as an enzymatic molecular flask for light-driven hydrogen production
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论文类型：期刊论文
发表时间：2017-01-01
发表刊物：RSC ADVANCES
收录刊物：SCIE、EI
卷号：7
期号：77
页面范围：48989-48993
ISSN号：2046-2069
摘要：A positively charged redox-active metal-organic triangle containing three redox-active copper centres was developed to encapsulate anionic organic dyes (fluorescein) through a weak host-guest interaction for photocatalytic hydrogen production. The unique geometry enforces a distorted square planar coordination suitable for proton reduction. Control experiments with a mononuclear copper complex as a reference photocatalyst and inactive ATP as an inhibitor were performed to confirm this enzymatic photocatalytic behaviour.