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Enhanced photovoltaic characteristics of solar cells based on n-type triphenodioxazine derivative

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Indexed by:期刊论文

Date of Publication:2008-12-01

Journal:MICROELECTRONICS JOURNAL

Included Journals:SCIE、EI、Scopus

Volume:39

Issue:12

Page Number:1568-1571

ISSN No.:0026-2692

Key Words:Polymer; Absorption spectra; Photoluminescence; Photovoltaics

Abstract:Polymer solar cells based on poly (2-methoxy-5-(2'-ethyl-hexyloxy)-1, 4-phenylene vinylene) (MEH-PPV):1-(3-methoxycarbonyl)-propyl-1-1-phenyl-(6,6)C61(PCBM):3, 10-di(trifluoromethane) triphenodioxazine (TFTD) was fabricated using spin coating technology. The absorption spectra of MEH-PPV: PCBM: TFTD film coated from chlorobenzene solution was broadened and showed higher intensity compared with that of the pure MEH-PPV. The TFTD acting as electron acceptors in combination with PCBM induced the photoluminescence (PL) quenching of MEH-PPV, which were associated with the photoinduced charge transfer characteristics of composite film. Further, a photovoltaic conversion efficiency up to 1.03% under 16.7 mW/cm(2) white light illumination was achieved in the MEH-PPV: PCBM: TFTD system. (c) 2008 Elsevier Ltd. All rights reserved.

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