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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：校长助理
其他任职：精细化工国家重点实验室副主任，辽宁省低碳资源高值化利用重点实验室主任
性别：男
毕业院校：中科院山西煤化所
学位：博士
所在单位：化工学院
学科：工业催化. 化学工艺. 能源化工
办公地点：大连市凌工路2号大连理工大学西部校区化工楼，邮编：116024
联系方式：0411-84986112
电子邮箱：anhuilu@dlut.edu.cn
Cobalt Phthalocyanine-Graphene Oxide Nanocomposite: Complicated Mutual Electronic Interaction
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论文类型：期刊论文
发表时间：2013-02-28
发表刊物：JOURNAL OF PHYSICAL CHEMISTRY C
收录刊物：SCIE、EI、Scopus
卷号：117
期号：8
页面范围：3785-3788
ISSN号：1932-7447
摘要：Through the adsorption/intercalation of cobalt phthalocyanine (CoPc) onto/into graphene oxide (GO) layers, CoPc-GO nanocomposite was prepared via a simple solvent evaporation method driven by the electronic interaction between CoPc and GO. The interaction between GO and CoPc has been studied in detail by various methods. The result suggests that the interaction does not follow a simple donor-acceptor mode, but, instead, it is complicated two-way process including the transfer of electron from the graphitic domain to the adsorbed/intercalated CoPc, and a feedback from the Co ions through the ligand-like attacking of oxygen functional groups of GO to the central cobalt ions. The obtained structural hybrid materials have potential in the electrochemical detection of the compounded medicine.