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论文类型：期刊论文

发表时间：2013-02-07

发表刊物：NANOSCALE

收录刊物：SCIE、EI、PubMed、ESI高被引论文、Scopus

卷号：5

期号：3

页面范围：1168-1175

ISSN号：2040-3364

摘要：Dopamine is an excellent and flexible agent for surface coating of inorganic nanoparticles and contains unusually high concentrations of amine groups. In this study, we demonstrate that through a controlled coating of a thin layer of polydopamine on the surface of alpha-Fe2O3 in the dopamine aqueous solution, followed by subsequent carbonization, N-doped carbon-encapsulated magnetite has been synthesized and shows excellent electrochemical performance as anode material for lithium-ion batteries. Due to the strong binding affinity to iron oxide and excellent coating capability of this new carbon precursor, the conformal polydopamine derived carbon is continuous and uniform, and its thickness can be tailored. Moreover, due to the high percentage of nitrogen content in the precursor, the resulting carbon layer contains a moderate amount of N species, which can substantially improve the electrochemical performance. The composites synthesized by this facile method exhibit superior electrochemical performance, including remarkably high specific capacity (>800 mA h g(-1) at a current of 500 mA g(-1)), high rate capability (595 and 396 mA h g(-1) at a current of 1000 and 2000 mA g(-1), respectively) and excellent cycle performance (200 cycles with 99% capacity retention), which adds to the potential as promising anodes for the application in lithium-ion batteries.