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论文类型：期刊论文

发表时间：2017-01-01

发表刊物：RSC ADVANCES

收录刊物：SCIE、EI、Scopus

卷号：7

期号：52

页面范围：33012-33019

ISSN号：2046-2069

摘要：Rational design and successful synthesis of highly efficient, long-term stable and low-cost bifunctional electro-catalysts are vital for commercialized application of rechargeable zinc-air batteries. Herein, a series of composite catalysts of different contents of CoSb3 alloy nanoparticles wrapped with N-doped carbon layers (CoSb3@NCL) have been synthesized by a simple one-step pyrolytic process. The optimized catalyst (CoSb3@NCL-30) exhibits excellent catalytic activities for both the ORR and OER in alkaline medium, which can be competitive with the Pt/ C catalyst (20%). More importantly, a real rechargeable zinc-air battery with the CoSb3@NCL-30 catalyst serving as an air cathode exhibits outstanding electrochemical properties and excellent cycling stability (the overall increment of the voltage gap was only 0.1 V after 60 hours), making it possible to replace expensive noble metal-based catalysts for actual application in rechargeable zinc-air batteries.