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个人信息Personal Information
副教授
硕士生导师
性别:男
毕业院校:吉林大学
学位:博士
所在单位:机械工程学院
学科:车辆工程. 材料学
办公地点:汽车学院实验室A303
联系方式:18941135528
电子邮箱:chengy@dlut.edu.cn
Cuboctahedral Sb2O3 Mesocrystals Organized from Octahedral Building Blocks: More than Self-Similarity
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论文类型:期刊论文
发表时间:2016-07-01
发表刊物:CRYSTAL GROWTH & DESIGN
收录刊物:SCIE、EI
卷号:16
期号:7
页面范围:3613-3617
ISSN号:1528-7483
摘要:Assembly of nanoparticle building blocks over multiple length scales into hierarchically ordered structures plays an essential role in the nonclassical crystallization pathway. Although random particle aggregates are constantly observed in crystallization experiments, mesocrystals with well shaped morphology and ordered hierarchical structure have been seldomly reported. Here, we describe the successful production of remarkable cuboctahedral Sb2O3 mesocrystals with hierarchical three-dimensional superstructures through a simple solution route. This is the first example of well-defined polyhedral mesocrystals with a cuboctahedral external morphology differing from the octahedral morphology of the building subunits. Electrostatic interactions between cetyltrimethylammonium cations (CTA(+)) and tartrate anions and hydrophobic interactions between the cetyltrimethylammonium bromide tails were supposed to be the driving force for the aggregation-based growth process. This novel mesocrystal formation breaks through the classical crystallization pattern and opens up a new pathway to construct mesoscale-transformed mesocrystals with hierarchical superstructures.