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    杨希川

    • 研究员     博士生导师   硕士生导师
    • 性别:男
    • 毕业院校:大连理工大学
    • 学位:博士
    • 所在单位:化工学院
    • 电子邮箱:yangxc@dlut.edu.cn

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    New Organic Dyes with a Phenanthrenequinone Derivative as the pi-Conjugated Bridge for Dye-Sensitized Solar Cells

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    论文类型:期刊论文

    发表时间:2013-06-27

    发表刊物:JOURNAL OF PHYSICAL CHEMISTRY C

    收录刊物:SCIE、EI、Scopus

    卷号:117

    期号:25

    页面范围:12936-12941

    ISSN号:1932-7447

    摘要:A series of organic dyes based on a phenanthrenequinone derivative have been employed for the first time as a it-conjugated bridge in the molecular design of D-pi-A structured organic dyes. Photophysical and electrochemical properties of dyes JH201-JH203 have been systematically investigated. The result shows that dye JH202 exhibits a higher molar extinction coefficient and widened absorption spectrum than dye JH201. Upon replacing the butoxyltriphenylamiine electron donor with phenothiazine, a bathochromic shift absorption spectrum for dye JH203 was observed. When applied in dye-sensitized solar cells (DSSCs), the device sensitized by JH203 yields the best photo-to-current conversion efficiency of 6.0% under standard AM 1.5G illumination (100 rnW/cm(2)) with a short-circuit photocurrent density (J(sc)) of 11.1 mA/cm(2), an open circuit photovoltage (V-oc) of 720 mV, and a fill factor (ff) of 74.9%. The maximum incident photo-to-current conversion efficiency reaches 87% at 460 nm.