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论文类型：期刊论文

发表时间：2010-10-01

发表刊物：7th International Conference on Bulk-Metallic Glasses

收录刊物：SCIE、EI、CPCI-S、Scopus

卷号：18

期号：10,SI

页面范围：1800-1802

ISSN号：0966-9795

关键字：Alloy design; Glasses; metallic; Thermal properties; Rapid solidification processing

摘要：The Ni-Nb-Zr bulk metallic glass composition was analyzed by our cluster-plus-glue-atom model using a eutectic-related binary cluster M-Ni6Nb6, M = 0.5Ni + 0.5Nb, which was derived from a eutectic phase Ni7Nb6 (Fe7W6 type). A composition formula [M-Ni6Nb4MZr]Ni-3 was then proposed, where the combination of one M and one Zr atom had an almost equal atomic size as a Nb atom to be substituted for. Alloy rods with 3 mm in diameter were obtained using copper mould suction casting. XRD results showed that compositions [M-Ni6Nb5-xMZrx]Ni-3, x = 0.76, 0.84, 0.92, 1, 1.08, 1.16 formed single glassy phases, conforming to the proposed formula. (C) 2010 Elsevier Ltd. All rights reserved.