Hits:

Indexed by:期刊论文

Date of Publication:2009-02-01

Journal:INORGANIC CHEMISTRY COMMUNICATIONS

Included Journals:SCIE

Volume:12

Issue:2

Page Number:72-75

ISSN No.:1387-7003

Key Words:Coordination polymer; Cadmium(II); Dinuclear building block; Photoluminescence

Abstract:A novel cadmium(II) coordination polymer, [Cd(2)(pzdc)(2)(4,4'-bpy)(2)]center dot 4H(2)O (1) (H(2)pzdc = pyrazine-2,3-dicarboxylic acid; 4,4'-bpy=4,4'-bipyridine), has been synthesized by hydrothermal reaction of Cd(OAC)(2), H(2)pzdc and 4,4'-bpy. Single-crystal X-ray diffraction analysis reveals that 1 constructed from dinuclear building blocks has a three-dimensional (3-D) structure with rob topology. Fluorescent measurement of 1 exhibits strong blue-green emission in the solid state at room temperature, and its framework possess remarkable thermal stability. Crown Copyright (C) 2008 Published by Elsevier B.V. All rights reserved.