大连理工大学主页平台管理系统 Ye Junwei--junweiye-- Synthesis and characterization of a new framework cobalt phosphate with one-dimensional channel, Co-3(H2O)(4)(PO4)(2)

Paper Publications

Synthesis and characterization of a new framework cobalt phosphate with one-dimensional channel, Co-3(H2O)(4)(PO4)(2)

Hits:
Indexed by:
期刊论文
First Author:
Lin, Yuan
Correspondence Author:
Ye, JW (reprint author), Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116012, Peoples R China.
Co-author:
Ning, Guiling,Ye, Junwei,Fan, Yong,Wang, Li
Date of Publication:
2008-01-01
Journal:
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Included Journals:
SCIE
Document Type:
J
Volume:
634
Issue:
6-7
Page Number:
1145-1148
ISSN No.:
0044-2313
Key Words:
cobalt; cobalt phosphate; crystal structure; hydrothermal synthesis
Abstract:
A new cobalt phosphate, Co-3(H2O)(4)(PO4)(2) (1) has been synthesized under mild hydrothermal conditions and characterized by single crystal X-ray diffraction. Crystal data for 1: orthorhombic system, Pnma, a = 10. 582(2) angstrom, b = 18.289(4) angstrom, c = 5.0236(10) angstrom, V = 972.2(3) angstrom(3), Z = 4. The compound displays complex threedimensional framework containing one-dimensional 8-membered ring channels. In this crystal structure, CoO4 and PO4 tetrahedra connect each other by sharing-vertex to form the infinite two-dimensional sheet which contains the edge-sharing four ring chain and double zig-zag chain, then these sheets are pillared by CoO2(H2O)(4) octahedra.

Pre One:Facile synthesis of mono-dispersed micro-parallelepiped anhydrous magnesium carbonate

Next One:新型微孔稀土金属配位聚合物的合成、结构及性能研究