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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：吉林大学
学位：博士
所在单位：化工学院
学科：化学工艺. 功能材料化学与化工. 无机化学
办公地点：大连理工大学西部校区化工综合楼D401
联系方式：0411-84986067（办公室） junweiye@dlut.edu.cn
电子邮箱：junweiye@dlut.edu.cn
Three-dimensional Ln(III)-Mn(II) metal organic frameworks constructed from Rod-shaped molecular building blocks: Syntheses, structures and magnetic properties
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论文类型：期刊论文
发表时间：2011-06-01
发表刊物：INORGANIC CHEMISTRY COMMUNICATIONS
收录刊物：SCIE
卷号：14
期号：6
页面范围：889-892
ISSN号：1387-7003
关键字：Heterometallic MOFs; Rod-shaped MBBs; Hydrothermal synthesis; Magnetic properties
摘要：The hydrothermal reaction of Ln(III) nitrate, Mn(II) sulfate hydrate with 5-nitroisophthalic acid (H(2)NIPH) produced two novel metal organic frameworks (MOFs), [Ln(2)Mn(NIPH)(4)(H(2)O)(4)]center dot 6H(2)O [Ln = Eu (1), Nd (2)], which represent the first examples of three-dimensional Ln(III)-Mn(II) heterometallic MOFs based on rod-shaped molecular building blocks (MBBs). In the structures, two LnO(9) polyhedra and one MnO(6) polyhedron are bridged in a corner-sharing fashion to form a trinuclear unit [Ln(2)MnO(20)], which is further connected to each other by carboxylate groups to give a [Eu(2)MnO(20)]-(O-C-O)(2)-[Eu(2)MnO(20)] heterometallic rod. The thermal properties and magnetic properties of 1 and 2 have been investigated in the solid state. (C) 2011 Elsevier B.V. All rights reserved.