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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：吉林大学
学位：博士
所在单位：化工学院
学科：化学工艺. 功能材料化学与化工. 无机化学
办公地点：大连理工大学西部校区化工综合楼D401
联系方式：0411-84986067（办公室） junweiye@dlut.edu.cn
电子邮箱：junweiye@dlut.edu.cn
Colorimetric 'naked-eye' sensor for anions based on conformational flexible tripodal receptor
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论文类型：期刊论文
发表时间：2011-06-01
发表刊物：JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
收录刊物：Scopus、SCIE
卷号：70
期号：1-2
页面范围：115-119
ISSN号：0923-0750
关键字：Amide-pyridinium; Tripodand; Anion sensing; Conformational change
摘要：A new tripodal receptor for anion sensing based on amide-pyridinium as recognition site and nitro-benzene as signaling unit was designed and successfully synthesized. This receptor showed high selectivity and strong binding affinity toward AcO(-) over the investigated anions, especially over H(2)PO(4) (-). Addition of AcO(-) induced clear color change of solution from colorless to yellow, realizing the "naked-eye" detection. UV-Vis and (1)H NMR experiments indicated the selectivity might origin from the synergistic effects arising from hydrogen bonding, electrostatic interactions and conformational change.