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论文类型：期刊论文

发表时间：2014-04-01

发表刊物：JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS

收录刊物：SCIE、EI

卷号：25

期号：4

页面范围：1751-1756

ISSN号：0957-4522

摘要：Si-Al-Zn alloy melts were used for silicon purification by the solvent refining process. The effect of metal Zn addition on alloy macrostructure, primary Si morphology, as well as B distribution in Si-Al alloy during solvent refining process was studied in this work. The three main results were as follows. First, with the increasing of Zn content in Si-Al alloy, the primary silicon changed from slender plate-like to irregular and short, meanwhile the distribution of primary silicon changed from bottom to central and top. Second, the more Zn content in Si-Al alloy, the more inclusions of eutectic melts will be in primary silicon, which results in diffusion difficulty of impurity B in inclusions. Third and last, with increasing Zn content, the refining ratio of B increased gradually and removal fraction of B decreased accordingly.