苯基三氟硼酸钾催化的硅烷还原羰基化合物成醇反应
Release Time:2019-11-04 Hits:
Indexed by: Journal Papers
Date of Publication: 2019-05-01
Journal: 有机化学
Included Journals: PKU、SCIE
Volume: 39
Issue: 5
Page Number: 1411-1416
ISSN: 0253-2786
Key Words: 羰基还原;有机硅烷;苯基三氟硼酸钾
Abstract: 研究了以有机硅烷为还原剂选择性还原羰基的反应,在2.5 mol％ C6H5BF3K,2.2 epuiv.(EtO)3SiH作用下,甲醇为溶剂,室温下将羰基还原为醇.以中等至较高产率得到目标产物.该方法在羰基还原上表现出良好的选择性,为羰基还原提供了一种新的方法.
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