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论文类型：会议论文

发表时间：2013-01-01

收录刊物：EI、CPCI-S、Scopus

卷号：35

页面范围：1087-1092

摘要：N,N-dimethyl-1,3-propanediamine (DMAPA) is an important fine organic chemical intermediate, is widely used in the manufacturing of surfactants, cosmetics, detergents, textiles, and lubricating oil additives. Although market need is growing increasingly, but research report about the manufacturing process of DMAPA is not investigated explicitly. The current preparation of DMAPA is a two-step batch reation. In the first step Dimethyl amine(DMA) and Acrylonitrile(ACN) as the starting materials lead to N, N-dimethyl-amino propionitrile(DMAPN). Then, DMAPN is hydrogenated to obtain DMAPA by Raney-Ni. Herein, we focus on realizing the two step in a continuous process using fixed bed. In the first step, the reaction conditions using fillers can achieve the effect of catalyst H-ZSM-5. Under an optimized the conditions 30 degrees C 1.0M Pa, LHSV 1.1 similar to 4h-1 and molar ration of 1.00:1.00, the reaction conversion and selectivity were higher than 99.5 %. Later, we exploit hydrogenation of DMAPN in a continuous process catalyzed by ZL-311-R. Under an optimized the conditions 70 degrees C, 6 MPa, LHSV 0.3 h-1, alkali liquor NaOH, the reaction conversion and selectivity were higher than 99.5 %. Realize synthesizing N, N-dimethyl-1,3-propanediamine continuously in the fixed bed and reaction conversion and selectivity were all higher than 99.5 % in the two step.