Title of Paper:Spin crossover and structural phase transition in homochiral and heterochiral Fe[(pybox)(2)](2+) complexes

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Date of Publication:2019-05-21

Journal:DALTON TRANSACTIONS

Included Journals:SCIE、EI

Volume:48

Issue:19

Page Number:6323-6327

ISSN No.:1477-9226

Abstract:Spin crossover and structural phase transition in three pairs of homochiral and heterochiral [Fe(pybox)(2)](2+) diastereomers were investigated through magnetic and crystallographic studies. Herein, we show that the spin transition properties of these compounds are strongly related to the homochiral or heterochiral assembly of the ligands and structural phase transition. Our work demonstrates that chirality is a feasible factor to modulate and influence the molecular geometry and thus the spin-crossover properties of complexes.