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Construction of fluorescence-tunable pyrido-fused benzimidazoles via direct intramolecular C-H amination under transition-metal-free conditions

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2014-10-08

Journal: RSC ADVANCES

Included Journals: Scopus、EI、SCIE

Volume: 4

Issue: 93

Page Number: 51268-51271

ISSN: 2046-2069

Abstract: A novel methodology was discovered to construct multi-phenyl substituted pyrido-fused benzimidazole (PBI) core frameworks via direct oxidative intramolecular C-H amination of alpha-unsubstituted pyridinium salts under transition-metal free conditions. The resulting highly pi-conjugated PBI derivatives exhibited highly tunable fluorescent emission not only in solution but also in the solid state.

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