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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：无
其他任职：精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工
办公地点：大连理工大学西部校区化工实验楼E-223
联系方式：0411-84986493
电子邮箱：sunlc@dlut.edu.cn
A novel ruthenium(II) tris(bipyridine)-zinc porphyrin-rhenium carbonyl triad: synthesis and optical properties
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论文类型：期刊论文
发表时间：2006-04-10
发表刊物：TETRAHEDRON
收录刊物：SCIE
卷号：62
期号：15
页面范围：3674-3680
ISSN号：0040-4020
关键字：porphyrin; ruthenium; rhenium; photophysics; electron transfer; energy transfer
摘要：A novel ruthenium(II) tris(bipyridine)-zinc porphyrin-rhenium carbonyl triads and its free base porphyrin derivative were synthesized and characterized by H-1, C-13 NMR, UV-vis, mass-spectrometry and elemental analysis. The redox potentials of the two Compounds were measured and compared to their corresponding reference complexes. The fluorescence and transient absorption spectra of the two complexes revealed the features of two different pathways for possible photoinduced intramolectular electron transfer or energy transfer in the triads. (c) 2006 Elsevier Ltd. All rights reserved.