孙立成
个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职:无
其他任职:精细化工国家重点实验室副主任、大连理工大学-瑞典皇家工学院分子器件联合研究中心主任
性别:男
毕业院校:大连理工大学
学位:博士
所在单位:化工学院
学科:应用化学. 精细化工
办公地点:大连理工大学西部校区化工实验楼E-223
联系方式:0411-84986493
电子邮箱:sunlc@dlut.edu.cn
扫描关注
Synthesis of chiral salen Mn(III) complexes covalently linked to Re(I)-based photosensitizers
点击次数:
论文类型:期刊论文
发表时间:2006-03-20
发表刊物:JOURNAL OF COORDINATION CHEMISTRY
收录刊物:SCIE
卷号:59
期号:5
页面范围:475-484
ISSN号:0095-8972
关键字:manganese complex; rhenium complex; heterobinuclear complex; chiral salen ligand; pyrrolidine; light-driven catalyst
摘要:Two Mn(III)Re(I) binuclear complexes were prepared as catalyst-photosensitizer models, in which the chiral pyrrolidine salen Mn(III) unit was covalently bonded to an Re(I) bipyridyl carbonyl moiety via a carboxamide linkage. The spectral and electrochemical properties of the Mn(III)Re(I) complexes were studied.