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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：中国科学院大连化学物理研究所
学位：博士
所在单位：环境学院
学科：环境科学. 环境工程
办公地点：大连理工大学西部校区环境楼B623
联系方式：tanf@dlut.edu.cn
Simultaneous detection of dopamine, uric acid, and ascorbic acid using SnO2 nanoparticles/multi-walled carbon nanotubes/carbon paste electrode
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论文类型：期刊论文
发表时间：2012-10-01
发表刊物：ANALYTICAL METHODS
收录刊物：SCIE、EI、Scopus
卷号：4
期号：10
页面范围：3283-3289
ISSN号：1759-9660
摘要：A novel SnO2 nanoparticles/multi-walled carbon nanotubes/carbon paste electrode (nanoSnO(2)/MWCNTs/CPE) was prepared for simultaneous detection of dopamine (DA), uric acid (UA), and ascorbic acid (AA) via cyclic voltammetry (CV) and differential pulse voltammetry (DPV). The novel nanoSnO(2)/MWCNTs/CPE electrode showed high electrochemical catalytic behavior for DA, UA, and AA. The three compounds could be completely separated on the electrode in CV and DPV at optimal conditions. DPV provided larger peak potential separations and higher response sensitivities of DA, UA, and AA compared to CV. In DPV, there are linear relationships between the peak currents and the concentrations in the ranges of 0.3-50 mu M for DA, 3-200 mu M for UA, and 0.1-5 mM for AA, with the detection limits (S/N = 3) of 0.03, 1, and 50 mu M for DA, UA, and AA, respectively. The proposed method was applied for the simultaneous detection of DA, UA, and AA in human urine samples, with recoveries of 91.0%, 97.4%, and 103.0% for DA, UA, and AA, respectively. The relative standard derivations (RSDs, n = 5) were 2.8-4.4%.
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