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论文类型：期刊论文

发表时间：2018-09-01

发表刊物：CATALYSTS

收录刊物：SCIE

卷号：8

期号：9

ISSN号：2073-4344

关键字：chemical looping reforming; perovskite; Ni-Co synergy

摘要：This paper describes the synthesis of a series of La1.4Sr0.6Ni1-xCoxO4 perovskite OCs using co-precipitation method by employing Co and Ni as the B-site components of perovskite and the synergetic effect of Co doping on chemical looping reforming of ethanol. A variety of techniques including N-2 adsorption-desorption, X-ray diffraction (XRD), transmission electron microscopy (TEM) and H-2 temperature-programmed reduction (TPR) were employed to investigate the physicochemical properties of the fresh and used OCs. The activity and stability in chemical looping reforming were studied in a fixed bed reactor at 600 degrees C and a S/C ratio of three. The synergetic effect between Ni and Co was able to enhance the catalytic activity and improve the stability of perovskite OCs. La1.4Sr0.6Ni0.6Co0.4O4 showed an average ethanol conversion of 92.4% and an average CO2/CO ratio of 5.4 in a 30-cycle stability test. Significantly, the H-2 yield and purity reached 11 wt.% and 73%, respectively. The Co doping was able to significantly improve the self-regeneration capability due to the increase in the number of oxygen vacancies in the perovskite lattice, thereby enhancing the sintering resistance. Moreover, Co promotion also contributes to the improved WGS activity.