
教授 博士生导师 硕士生导师
性别:男
毕业院校:大连理工大学
学位:博士
所在单位:化工学院
学科:应用化学
精细化工
生物化工
办公地点:西校区E-204
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发布时间:2019-03-09
论文类型:期刊论文
发表时间:2013-06-12
发表刊物:TETRAHEDRON LETTERS
收录刊物:Scopus、SCIE
卷号:54
期号:24
页面范围:3171-3175
ISSN号:0040-4039
关键字:BBL; Soluble polymer; Ladder conjugated; Organic semiconductor; Stille coupling
摘要:To improve the solubility of naphthalene bisanhydride (NTCA), four alkyl groups are incorporated to the naphthalene core via a five-step procedure. The new naphthalene bisanhydride derivative (TO-NTCA) shows much higher reactivity than the parent NTCA in the model condensations with ortho-diaminobenzene and 2-ethylhexylamine and gives corresponding soluble molecules with excellent yields. Hence, TO-NTCA is a potential monomer for condensations. (C) 2013 Elsevier Ltd. All rights reserved.