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Indexed by:期刊论文
Date of Publication:2008-07-15
Journal:JOURNAL OF MEMBRANE SCIENCE
Included Journals:SCIE、EI
Volume:320
Issue:1-2
Page Number:303-309
ISSN No.:0376-7388
Key Words:MFI membrane; alpha-alumina support; gas permeation; high permeance; ideal separation factor
Abstract:MFI membrane with high permeance was successfully synthesized on the macroporous (pore size of 3-4 mu m) alpha-Al2O3 tubular support with a novel modified secondary growth method. Before the crystallization, the seeded support was wrapped with Teflon tape in order to focalize the growth of crystals in the region of seed layer. The as-synthesized membrane was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and single-gas permeation testing. The results indicated that the assynthesized membrane had a thickness of 6-8 mu m similar to the thickness ofthe seed layer and exhibited high gas permeance. At room temperature, the permeance of H-2 and the ideal separation factor of H-2/SF6 reached 1.64 x 10(-6) mol m(-2) s(-1) Pa-1 and 71, respectively. The permeance of single-gas increased with the increasing of temperature. The ideal separation factors of H-2/i-C4H10 and H-2/SF6 decreased with the increasing of temperature from 298 to 473 K. At 473 K, the ideal separation factors of H-2/i-C4H10 and H-2/SF6 were 12.16 and 11.08, which were still higher than their Knudsen ratios of 5.39 and 8.54, respectively. (C) 2008 Elsevier B.V. All rights reserved.