Indexed by:期刊论文
Date of Publication:1998-07-20
Journal:合成橡胶工业
Issue:04
Page Number:36-37
ISSN No.:1000-1255
Key Words:丁二烯;苯乙烯;负离子聚合;四氢呋喃;四氯化锡;己二酸二乙酯;偶联反应
Abstract:以ｎ－ＢｕＬｉ为引发剂，ＴＨＦ／ｎ－ＢｕＬｉ（摩尔比）为８０～３００，在丁二烯、苯乙烯负离子共聚体系中加入ＳｎＣｌ４或己二酸二乙酯（ＤＥＡＰ）进行偶联反应，研究了ＴＨＦ和偶联剂用量、偶联反应温度和时间及共聚物不同链末端结构对偶联反应的影响。结果表明，ＳｎＣｌ４的偶联效率（５１．６％）高于ＤＥＡＰ（４３．８％），且该体系共聚物链末端结构对偶联效率无影响；ＳｎＣｌ４较佳的偶联反应条件为：５０℃，３０ｍｉｎ，ＳｎＣｌ４／ｎ－ＢｕＬｉ为０．１
Associate Professor
Supervisor of Doctorate Candidates
Supervisor of Master's Candidates
Gender:Male
Alma Mater:Dalian University of Technology
Degree:Doctoral Degree
School/Department:Dept. of Polymer Materials
Discipline:Polymer Materials. Polymer Chemistry and Physics. Chemistry and Chemical Engineering of Functional
Business Address:Chemical Experiment Building A303, West Campus
Contact Information:Tel：+86-411-84986101
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