Indexed by:会议论文
Date of Publication:2009-08-18
Page Number:1
Key Words:阴离子聚合;1;2-聚丁二烯;氢化反应;聚乙烯;聚丁烯-1
Abstract:本文以n-BuLi为引发剂,环己烷为溶剂40℃条件下进行丁二烯阴离子聚合,根据40℃聚合动力学,当反应到达预设时间后加入极性调剂二哌啶乙烷(DPE)5℃条件下聚合,得到一系列不同嵌段比的1,4-b-1,2-聚丁二烯(PBd),1,2段中1,2-PBd结构含量>98%。然后采用镍
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