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论文类型：期刊论文

发表时间：2014-04-24

发表刊物：INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

收录刊物：SCIE、EI、Scopus

卷号：39

期号：13

页面范围：7069-7076

ISSN号：0360-3199

关键字：Palladium membrane; Hydrogen separation; Bio-membrane; Electroless plating; Osmosis

摘要：Palladium membrane was prepared on the inner surface of alumina tube by bio-membrane assisted electroless plating combined with osmosis method (BELP). In this preparation technique, an egg-shell film not only served as a semipermeable membrane to form osmotic system for preparing palladium membrane, but also acted as a protection layer to prevent the contamination of the palladium membrane from the osmotic solution. Moreover, the plating solution was circulated through the tube side to promote the mass transfer on the solid liquid interface between the plating surface and the solution. The detailed depositing process of the palladium membrane was studied by scanning electron microscopy (SEM) and Energy dispersive X-ray spectroscopy (EDXS). Both long term operation and temperature cycling test carried out for hydrogen and nitrogen permeation confirmed that the palladium membrane was stable. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.