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论文类型： 期刊论文

发表时间： 2014-12-21

发表刊物： NANOSCALE

收录刊物： SCIE、PubMed、Scopus

卷号： 6

期号： 24

页面范围： 14617-14621

ISSN号： 2040-3364

摘要： Our studies show that VSi12- adopts a V-centered hexagonal prism with a singlet spin state. The addition of the second V atom leads to a capped hexagonal antiprism for V2Si12- in a doublet spin state. Most interestingly, V3Si12- exhibits a ferrimagnetic, bicapped hexagonal antiprism wheel-like structure with a total spin of 4 mu(B).