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个人信息Personal Information
副教授
博士生导师
硕士生导师
性别：女
毕业院校：美国伊利诺伊大学香槟
学位：博士
所在单位：化工学院
学科：高分子材料. 高分子化学与物理
办公地点：西部校区化工实验楼A207
联系方式：nzheng@dlut.edu.cn
电子邮箱：nzheng@dlut.edu.cn
Chiral catalyst-directed site-selective functionalization of hydroxyl groups in carbohydrates
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论文类型：期刊论文
发表时间：2017-01-01
发表刊物：JOURNAL OF CARBOHYDRATE CHEMISTRY
收录刊物：SCIE
卷号：36
期号：4-6
页面范围：143-161
ISSN号：0732-8303
关键字：Site-selectivity; chiral catalyst; functionalization; hydroxyl groups
摘要：Carbohydrates perform essential roles in living organisms. Recently, a series of breakthroughs emerged in chiral catalyst-directed site-selective functionalization of carbohydrates. In this review site-selective functionalization of cis-diols, trans-diols and others mediated by chiral catalysts was discussed. The reaction types covered are mainly acylation, acetalization, glycosidation, thiocarbonylation, silylation, phosphorylation, sulfonylation, and so on. Some important site-selective methodologies used in the synthesis of saccharides are also elaborated.