|
个人信息Personal Information
副教授
博士生导师
硕士生导师
性别：女
毕业院校：美国伊利诺伊大学香槟
学位：博士
所在单位：化工学院
学科：高分子材料. 高分子化学与物理
办公地点：西部校区化工实验楼A207
联系方式：nzheng@dlut.edu.cn
电子邮箱：nzheng@dlut.edu.cn
Palladium-Catalyzed Regioselective and Diastereoselective C-Glycosylation by Allyl-Allyl Coupling
点击次数：
论文类型：期刊论文
发表时间：2021-03-13
发表刊物：ADVANCED SYNTHESIS & CATALYSIS
卷号：363
期号：3
页面范围：846-850
ISSN号：1615-4150
关键字：C-glycosylation; Allyl-allyl coupling; Pd-π -allyl intermediate; Achmatowicz rearrangement products; Methylcoumarins
摘要：A Pd-catalyzed C-glycosylation reaction was developed by allyl-allyl coupling process using Achmatowicz rearrangement products as donors and methylcoumarins as acceptors under mild conditions. This method featured regio- and diastereoselectivities, stereodivergent synthesis of C-glycosides. The glycosyl donors with controlled stereodiversity and glycosyl acceptors with fluorescent performace further highlighted this methodology.