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Ag-graphene/PEG composite phase change materials for enhancing solar-thermal energy conversion and storage capacity

2021-03-06 Hits:

Indexed by:期刊论文

First Author:Zhang, Yuang

Correspondence Author:Jiasheng Wang,Qiu, Jinjing,Jin, Xin,Umair, Malik Muhammad,Lu, Rongwen,zhangshufen,tang bingtao

Date of Publication:2021-03-06



Page Number:83-90

ISSN No.:0306-2619

Key Words:Ag-GNS; Phase change materials; Photothermal conversion; Sunlight-driven

Abstract:In view of the excellent characteristic of thermal energy storage, phase change materials (PCMs) are of great significance for improving the efficiency of solar thermal energy utilization. However, the direct thermal effect of visible-light (40% of solar radiation) is very low. In order to improve the capabilities of visible-light absorption and photothermal conversion, we reported novel and efficient sunlight-driven PCMs based on polyethylene glycol (PEG) supported by Ag nanopardcle-functionalized graphene nanosheets (Ag-GNS). The multi folded layered structure provides Ag-GNS a large surface area to support PEG for achieving the shape stability before and after phase transition. Meanwhile, based on the local surface plasma resonance effect of Ag, Ag has high visible light selective absorption and infrared reflectance, which can give Ag-GNS enhanced light absorption capacity and reduced thermal radiation. So Ag-GNS/PEG can harvest sunlight and convert light to thermal energy with significantly higher efficiency (eta = 88.7-92.0%). Moreover, Ag-GNS/PEG composites exhibit enhanced thermal conductivities (49.5-95.3%), high energy storage densities (>166.1 J/g), high thermal energy storage/release rates and outstanding form-stable properties. Therefore, this novel sunlight-driven composite can be potentially used for clean and efficient utilization of solar energy.

Date of Publication:2021-03-06

Jiasheng Wang

Gender:Male Alma Mater:大连理工大学 Degree:Doctoral Degree School/Department:化工学院盘锦分院 Business Address:大连理工大学盘锦D01-309 E-Mail:jswang@dlut.edu.cn