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个人信息Personal Information
高级工程师
硕士生导师
性别：女
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学
办公地点：理工西部校区实验楼F308
联系方式：rzhang@dlut.edu.cn
电子邮箱：rzhang@dlut.edu.cn
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A Ligand-Free Copper-Catalyzed Decarboxylative Trifluoromethylation of Aryliodides with Sodium Trifluoroacetate Using Ag2O as a Promoter
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论文类型：期刊论文
发表时间：2011-07-01
发表刊物：SYNLETT
收录刊物：SCIE
期号：12
页面范围：1713-1716
ISSN号：0936-5214
关键字：copper-catalyzed; trifluoromethylation; decarboxylative; silver oxide; cross-coupling
摘要：A practical and ligand-free Cu-catalyzed decarboxylative trifluoromethylation of aryl iodides with sodium trifluoroacetate using Ag2O as a promoter was reported. A variety of trifluoromethyl-substituted aromatics are synthesized in moderate to excellent yields and with wide functional-group tolerance under relatively mild reaction conditions.