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Synthesis and characterization of poly(ether amide)s containing bisphthalazinone and ether linkages

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Indexed by:期刊论文

Date of Publication:2005-04-01

Journal:CHINESE CHEMICAL LETTERS

Included Journals:Scopus、SCIE、ISTIC

Volume:16

Issue:4

Page Number:437-439

ISSN No.:1001-8417

Key Words:poly(ether amide) s; bisphthalazinone; thermal stability; solubility

Abstract:A novel aromatic diacid, 4, 4'-bis[2-(4-carboxyphenyl)phthalazin-l-one-4-yl]-bisphenyl ether M, containing bisphthalazinone and ether linkages was prepared from nucleophilic substitution of p-chlorobenzonitrile with the bisphenol-like monomer 1, followed by alkaline hydrolysis of the intermediate dinitrile II. A series of poly(ether amide)s containing bisphthalazinone and ether linkages derived from diacid III and aromatic diamines were synthesized by one-step solution condensation polymerization using triphenyl phosphite and pyridine as condensing agents. Moreover, the properties of poly(ether amide)s including thermal stability, solubility and crystallinity were also studied.

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