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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：中国化学会创始会士、常务理事，中国化工学会会士
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工. 化学生物学
办公地点：大连理工大学西部校区知顺楼F-202#
http://peng-group.dlut.edu.cn/
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Regioselective hydrogenation of p-phenylphenol to p-cyclohexylphenol over Pd/C catalyst in THF solvent
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论文类型：期刊论文
发表时间：2008-08-30
发表刊物：CATALYSIS COMMUNICATIONS
收录刊物：Scopus、EI、SCIE
卷号：9
期号：14
页面范围：2345-2348
ISSN号：1566-7367
关键字：Pd/C catalyst; regioselective hydrogenation; p-cyclohexylphenol; p-phenylphenol
摘要：Regioselective hydrogenation of p-phenyl phenol (p-PP) to p-cyclohexyl phenol (p-CP) was performed over 10 wt.% Pd/C catalyst in THF solvent. The selectivity of p-CP was up to 92.3% at 413 K under 3.5 MPa with 100% conversion of p-PP. The desired product could be easily separated from the reaction mixture by washing with aqueous NaOH following extraction by toluene. The reaction mechanism was discussed. (C) 2008 Elsevier B.V. All rights reserved.