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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：中国化学会创始会士、常务理事，中国化工学会会士
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工. 化学生物学
办公地点：大连理工大学西部校区知顺楼F-202#
http://peng-group.dlut.edu.cn/
联系方式：大连理工大学西部校区知顺楼F-202 辽宁省大连市高新区凌工路2号，大连116024 课题组网址：http://peng-group.dlut.edu.cn/ E-mail: pengxj@dlut.edu.cn
电子邮箱：pengxj@dlut.edu.cn
8-{4-[N,N-bis(2-chloroethyl)amino]phenyl}-4,4-difluoro-1,3,5,7-tetrameth yl-4-bora-3a,4a-diaza-s-indacene
点击次数：
论文类型：期刊论文
发表时间：2007-07-01
发表刊物：ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
收录刊物：SCIE、Scopus
卷号：63
期号：7
页面范围：O3317-U4427
ISSN号：1600-5368
摘要：In the title compound, C23H26BCl2F2N3, the three boron-dipyrromethene (BODIPY) fused heterocyclic rings are almost planar [r.m.s. deviation = 0.024 (9) angstrom]. The dihedral angle between the planes of the benzene ring and the BODIPY fused-ring fragment is 74.9 (8)degrees. The sp(3)-hybridized B centre appears as a slightly distorted tetrahedron, with N-B-N and F-B-F angles of 106.82 (15) and 109.83 (17)degrees, respectively. The two B-N distances in the central ring are almost identical, indicating delocalization of their charge. The two Cl atoms are disordered, with occupancies of approximately 0.85:0.15 and 0.60:0.40.