个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职:Director, State Key laboratory of Fine Chemicals
其他任职:精细化工国家重点实验室主任、国务院学科评议组成员
性别:男
毕业院校:大连理工大学
学位:博士
所在单位:化工学院
学科:应用化学. 精细化工. 化学生物学
办公地点:大连理工大学精细化工国家重点实验室
西部校区化工实验楼F-202#
http://peng-group.dlut.edu.cn/
联系方式:大连理工大学精细化工国家重点实验室 西部校区化工实验楼F-202 辽宁省大连市高新区凌工路2号,大连116024 Tel: 0411-84986306; Fax: 0411-84986292;课题组网址:http://peng-group.dlut.edu.cn/
电子邮箱:pengxj@dlut.edu.cn
Studies of a series of novel rhenium(I) bipyridyl dyes for solar cells
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论文类型:期刊论文
发表时间:2005-05-01
发表刊物:CHINESE CHEMICAL LETTERS
收录刊物:Scopus、SCIE、ISTIC
卷号:16
期号:5
页面范围:677-680
ISSN号:1001-8417
关键字:rhenium(I) bipyridyl complex; redox potential; electron transfer driving force
摘要:A series of novel rhenium(I) 2,2'-bipyridyl complexes [fac-Re(4,4'-di-COOEt-bpy)-(CO)(3)(Xpy)PF6], where bpy is 2,2'-bipyridine, py is pyridine and X is 3-methyl, 3-hydroxy, or 3-amino, were synthesized, their photophysical and electrochemical properties were studied. The Re(II/I) oxidation potentials decreased as the X group becomes more electron donating from H to 3-methyl, 3-hydroxy, or 3-amino, which might be a very convenient ways for adjusting the electron transfer driving force.