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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：中国化学会创始会士、常务理事，中国化工学会会士
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工. 化学生物学
办公地点：大连理工大学西部校区知顺楼F-202#
http://peng-group.dlut.edu.cn/
联系方式：大连理工大学西部校区知顺楼F-202 辽宁省大连市高新区凌工路2号，大连116024 课题组网址：http://peng-group.dlut.edu.cn/ E-mail: pengxj@dlut.edu.cn
电子邮箱：pengxj@dlut.edu.cn
Studies of a series of novel rhenium(I) bipyridyl dyes for solar cells
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论文类型：期刊论文
发表时间：2005-05-01
发表刊物：CHINESE CHEMICAL LETTERS
收录刊物：Scopus、SCIE、ISTIC
卷号：16
期号：5
页面范围：677-680
ISSN号：1001-8417
关键字：rhenium(I) bipyridyl complex; redox potential; electron transfer driving force
摘要：A series of novel rhenium(I) 2,2'-bipyridyl complexes [fac-Re(4,4'-di-COOEt-bpy)-(CO)(3)(Xpy)PF6], where bpy is 2,2'-bipyridine, py is pyridine and X is 3-methyl, 3-hydroxy, or 3-amino, were synthesized, their photophysical and electrochemical properties were studied. The Re(II/I) oxidation potentials decreased as the X group becomes more electron donating from H to 3-methyl, 3-hydroxy, or 3-amino, which might be a very convenient ways for adjusting the electron transfer driving force.