
Professor
Supervisor of Doctorate Candidates
Supervisor of Master's Candidates
Title : Director of R & D Center of Membrane Science and Technology
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化学交联法在质子交换膜制备中的应用
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Date of Publication:2006-01-01
Journal:高分子材料科学与工程
Volume:22
Issue:4
Page Number:28
ISSN:1000-7555
Abstract:It is an efficient way to improve the properties of proton exchange
membranes (PEMs) by the method of chemical cross-linking. The
cross-linked PEMs have the advantages of low water uptake, low methanol
crossover, high thermal and mechanical stability. There are three
methods to perform cross-linking. These are sulfonation of a
cross-linked polymer, cross- linking of a sulfonated polymer, and
cross-linking of a polymer blending system. Different cross-
linkingmethods lead to different cross-linking sites and consequently
different properties of the PEMs. Cross-linking degree, ion exchange
capacity or cross-linker species may have profound effects on
microstructure and properties of the cross-linked membranes. They should
be optimized in order to make the best of the properties of cross-linked
PEMs.
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