Title of Paper:Quaternized poly(ether ether ketone) hydroxide exchange membranes for fuel cells

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Date of Publication:2011-06-15

Journal:JOURNAL OF MEMBRANE SCIENCE

Included Journals:SCIE、EI

Volume:375

Issue:1-2

Page Number:204-211

ISSN No.:0376-7388

Key Words:Hydroxide exchange membrane; Poly (ether ether ketone); Chloromethylation; Quaternization; Fuel cell

Abstract:Chloromethylated PEEK (CMPEEK) was successfully synthesized for the first time by concentrated sulfuric acid as the solvent and its degree of chloromethylation (DC) was controlled (38-98%) by varying the chloromethylation time. The sulfo nation of PEEK was confirmed to be negligible during the chloromethylation by (1)H NMR analysis. CMPEEKs are soluble in high-boiling-point solvents, which makes it possible to prepare CMPEEK membranes. Subsequently, it was quaternized and ion-exchanged by NaOH to form quaternized PEEK hydroxide (QAPEEKOH) membrane. The ion exchange capacity of QAPEEKOH membranes ranges from 0.43 to 1.35 mmol g(-1), and the corresponding degree of quaternization of chloromethyl group increases from 35% to 61%. QAPEEKOH membranes from DC of 38-70% have appropriate water uptake (<= 145%) and moderate swelling ratio (<= 27%) even at 60 degrees C. More importantly, their hydroxide conductivities, such as 12 mS cm(-1) at 30 degrees C and 0.95 mmol g(-1) of IEC, are higher than those of most other quaternized aromatic polymer membranes. TGA shows that QAPEEKOH has high thermal stability (T(OD): 148 degrees C). All the above properties indicate that QAPEEKOH membrane is very promising for the potential application in hydroxide exchange membrane fuel cells. (C) 2011 Elsevier B.V. All rights reserved.