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纳米和微米ZSM-5分子筛在焦化苯乙基化反应体系中稳定性比较

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Date of Publication:2022-10-06

Journal:石油学报 石油加工

Issue:1

Page Number:46-50

ISSN No.:1001-8719

Abstract:The ethylation of coking benzene over ZSM-5 zeolites with different crystal size was investigated. The results showed that the difference in catalyst stability of nano-sized and micro-sized ZSM-5 zeolites in ethylation depended strongly on the type of ethylation agent. When ethanol was used as the ethylating agent, ZSM-5-m-25 prepared from micro-sized ZSM-5 zeolite exhibited better catalysis stability than ZSM-5-n-25 prepared from nano-sized ZSM-5 zeolite. When ethyene was used as the ethylating agent, ZSM-5-n-25 showed better catalyst stability than ZSM-5-m-25.

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