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Increased active sites and their accessibility of a N-doped carbon nanotube carbocatalyst with remarkably enhanced catalytic performance in direct dehydrogenation of ethylbenzene

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Indexed by:期刊论文

Date of Publication:2015-01-01

Journal:RSC ADVANCES

Included Journals:SCIE、EI、Scopus

Volume:5

Issue:65

Page Number:53095-53099

ISSN No.:2046-2069

Abstract:This work presents an efficient and low-cost one-step strategy for simultaneously N-doping and increasing surface ketonic C=O groups and structural defects of a N-doped carbon nanotube (HN-CNT) through the explosive decomposition of hexamethylenetetramine (HTA) nitrate, a low-cost N, O-containing organic compound. The as synthesized HN-CNT demonstrates a 1.64 and 2.19 times higher steady-state styrene rate with 98.5% selectivity towards styrene for direct dehydrogenation (DDH) than that of the parent CNT and H-CNT prepared by the similar pyrolysis procedure to that for the HN-CNT except for replacing HTA nitrate with HTA.

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