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One-pot synthesis-assembly-separation of cucurbit[6]uril via SO3H-functionalized ionic liquids

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Indexed by:Journal Papers

Date of Publication:2014-12-01

Journal:JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY

Included Journals:SCIE

Volume:80

Issue:3-4

Page Number:457-461

ISSN No.:0923-0750

Key Words:Supramolecular; Cucurbituril; Ionic liquid; Anion; Microwave

Abstract:A novel microwave-assisted route to synthesize cucurbit[n]uril in SO3H-functionalized ionic liquids was reported, which enabled the automatic separation of cucurbit[6]uril through anion assembly. For the first time, the route has realized synthesis-assembly-separation of cucurbit[6]uril in one pot. The reaction yield and separation efficiency can be tuned by choice of anionic groups in ionic liquids.

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