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Indexed by:期刊论文

Date of Publication:2012-12-19

Journal:TETRAHEDRON LETTERS

Included Journals:SCIE、Scopus

Volume:53

Issue:51

Page Number:6995-6998

ISSN No.:0040-4039

Key Words:Sodium benzotriazolide; Iridium; Phosphoramidite ligand; Asymmetric allylation

Abstract:A highly enantioselective allylic substitution of sodium benzotriazolide has been attained in the presence of [Ir(COD)Cl](2)/phosphoramidite ligand L1 together with K3PO4 as an additive, producing enantioen-riched allylbenzotriazole compounds with up to 98% ee. (C) 2012 Elsevier Ltd. All rights reserved.