Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2012-12-19

Journal: TETRAHEDRON LETTERS

Included Journals: Scopus、SCIE

Volume: 53

Issue: 51

Page Number: 6995-6998

ISSN: 0040-4039

Key Words: Sodium benzotriazolide; Iridium; Phosphoramidite ligand; Asymmetric allylation

Abstract: A highly enantioselective allylic substitution of sodium benzotriazolide has been attained in the presence of [Ir(COD)Cl](2)/phosphoramidite ligand L1 together with K3PO4 as an additive, producing enantioen-riched allylbenzotriazole compounds with up to 98% ee. (C) 2012 Elsevier Ltd. All rights reserved.