Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2012-11-18

Journal: TETRAHEDRON

Included Journals: Scopus、SCIE

Volume: 68

Issue: 46

Page Number: 9413-9418

ISSN: 0040-4020

Key Words: Allylation; Iridium; Phosphoramidite ligand; Sodium 2-aminobenzenethiolate; Benzo-fused N,S-heterocycle

Abstract: The use of sodium 2-aminobenzenethiolate in the enantioselective iridium catalyzed allylic substitution with a range of methyl allyl carbonates allows the concise synthesis of the branch-type products with both excellent regio- and enantioselectivities, which are functionalized N,S-containing allylic intermediates for the formation of chiral benzo-fused N,S-heterocycles. (C) 2012 Elsevier Ltd. All rights reserved.