Hits:

Indexed by:期刊论文

Date of Publication:2012-11-18

Journal:TETRAHEDRON

Included Journals:SCIE、Scopus

Volume:68

Issue:46

Page Number:9413-9418

ISSN No.:0040-4020

Key Words:Allylation; Iridium; Phosphoramidite ligand; Sodium 2-aminobenzenethiolate; Benzo-fused N,S-heterocycle

Abstract:The use of sodium 2-aminobenzenethiolate in the enantioselective iridium catalyzed allylic substitution with a range of methyl allyl carbonates allows the concise synthesis of the branch-type products with both excellent regio- and enantioselectivities, which are functionalized N,S-containing allylic intermediates for the formation of chiral benzo-fused N,S-heterocycles. (C) 2012 Elsevier Ltd. All rights reserved.