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Iridium-Catalyzed Allylic Alkylations of Sodium Phenyl Selenide

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Indexed by:期刊论文

Date of Publication:2012-11-01

Journal:CHINESE JOURNAL OF CHEMISTRY

Included Journals:SCIE、Scopus

Volume:30

Issue:11,SI

Page Number:2647-2651

ISSN No.:1001-604X

Key Words:sodium phenyl selenide; allylation; iridium; phosphoramidite ligand; allyl phenyl selenide

Abstract:An iridium-catalyzed allylic substitution of sodium phenyl selenide with unsymmetrical allyl carbonates was accomplished, which produced the linear allyl phenyl selenides in 38%74% yields. An asymmetric iridium-catalyzed allylation of sodium phenyl selenide was presented as well.

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