Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2012-11-01

Journal: CHINESE JOURNAL OF CHEMISTRY

Included Journals: Scopus、SCIE

Volume: 30

Issue: 11,SI

Page Number: 2647-2651

ISSN: 1001-604X

Key Words: sodium phenyl selenide; allylation; iridium; phosphoramidite ligand; allyl phenyl selenide

Abstract: An iridium-catalyzed allylic substitution of sodium phenyl selenide with unsymmetrical allyl carbonates was accomplished, which produced the linear allyl phenyl selenides in 38%74% yields. An asymmetric iridium-catalyzed allylation of sodium phenyl selenide was presented as well.