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Indexed by:Journal Papers

Date of Publication:2008-06-30

Journal:CATALYSIS COMMUNICATIONS

Included Journals:SCIE、EI

Volume:9

Issue:11-12

Page Number:2117-2120

ISSN No.:1566-7367

Key Words:nitric oxide; selective catalytic reduction; ferrierite; C2H2 Eley-Rideal mode

Abstract:It is found that formamide species as a crucial intermediate of the selective catalytic reduction of NO by C2H2 Was produced by nitrate species reacting with acetylene in Eley-Rideal mode on H-ferrierite (HFER) based catalyst. The mode concerning the formamide intermediate formation was proposed for the first time in selective catalytic reduction of NO by hydrocarbons. Impregnation of 2% zirconium into HFER considerably favored the formation of formamide species, and therefore better catalytic activity for the title reaction was obtained on 2%Zr/HFER. (C) 2008 Elsevier B.V. All rights reserved.