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论文类型：期刊论文

第一作者：Ji, Min

通讯作者：Ji, M (reprint author), Dalian Univ Technol, Sch Chem, Dalian 116012, Peoples R China.

合写作者：Li, Xuefeng,Wang, Junhu,Zhu, Jianmin,Zhou, Liming

发表时间：2011-09-01

发表刊物：9th Congress on Catalysis Applied to Fine Chemicals (CAFC9)

收录刊物：SCIE、EI、CPCI-S、Scopus

卷号：173

期号：1

页面范围：28-31

ISSN号：0920-5861

关键字：Grafting tin chloride; Lewis acid; Support effect; Prins condensation

摘要：Grafting SnCl4 on inorganic support as a novel solid acid catalyst was used to catalyze the Prins condensation reaction of isobutene with formaldehyde to produce 3-methylbut-3-en-1-ol (MBOH). Three supports of SiO2, SiO2-Al2O3 and gamma-Al2O3 were used to prepare the catalysts, and the structure and acid property of the tin chloride species formed over different supports was investigated. It was found that the SnCl4 grafted on SiO2 exhibited high activity and selectivity at a low reaction temperature of 100 degrees C, with formaldehyde conversion of 55% and MBOH selectivity of 92%. The superior performance of SnClx-SiO2 catalyst was attributed to its low electron density of tin nucleus and strong Lewis acidity. (C) 2011 Elsevier B. V. All rights reserved.