Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2014-11-25

Journal: CHEMICAL COMMUNICATIONS

Included Journals: Scopus、PubMed、SCIE

Volume: 50

Issue: 91

Page Number: 14153-14156

ISSN: 1359-7345

Abstract: A series of nickel complexes containing N-5-pentadentate ligands with different amine-to-pyridine ratios were studied for electrochemical H-2 production in neutral water and the one with a diamine-tripyridine ligand displays a TON of up to 308000 over 60 h electrolysis at -1.25 V vs. SHE, with a Faradaic efficiency of similar to 91%.