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Indexed by:期刊论文

Date of Publication:2008-01-01

Journal:ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Included Journals:SCIE、PubMed

Volume:64

Issue:Pt 1

Page Number:M217-U2091

ISSN No.:1600-5368

Abstract:The title compound, [Fe-3(C8H8N2O)S-2(CO)(8)], was prepared by the direct reaction of Fe-3(CO)(12) and 5-methoxy-1H-benzoimidazole-2- thiol in tetrahydrofuran. Desulfurization took place readily to form a sulfide carbonyl cluster. The molecule contains a triangle consisting of three Fe atoms capped by two S atoms above and below. There are two Fe Fe bonds [2.6322 (5) and 2.5582 (5) angstrom] in the triangle; the length of the third edge [3.3987 (5) angstrom] is too long to represent an Fe-Fe bond.