Release Time:2019-03-10  Hits:

Indexed by: Journal Article

Date of Publication: 2008-01-01

Journal: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Included Journals: PubMed、SCIE

Volume: 64

Issue: Pt 1

Page Number: M217-U2091

ISSN: 1600-5368

Abstract: The title compound, [Fe-3(C8H8N2O)S-2(CO)(8)], was prepared by the direct reaction of Fe-3(CO)(12) and 5-methoxy-1H-benzoimidazole-2- thiol in tetrahydrofuran. Desulfurization took place readily to form a sulfide carbonyl cluster. The molecule contains a triangle consisting of three Fe atoms capped by two S atoms above and below. There are two Fe Fe bonds [2.6322 (5) and 2.5582 (5) angstrom] in the triangle; the length of the third edge [3.3987 (5) angstrom] is too long to represent an Fe-Fe bond.